Research in Hydrogeology

Research in hydrogeology in the Department of Earth and Environmental Sciences broadly includes field-based studies and mathematical modeling of ground-water flow, mass transport, and reactions in the subsurface. Past and present research projects include: 

Controls on ground-water composition in regional sedimentary aquifers
Lower Wilcox Aquifer: In the northern Gulf Coastal Plain of Arkansas, irrigation for rice and other crops has resulted in overexploitation of the Mississippi Valley alluvial aquifer.
An alternative water supply that is not extensively utilized is the confined lower Wilcox aquifer. Estifanos Haile (PhD candidate) has found that systematic changes in solute chemistry along the regional hydraulic gradient result from carbonate weathering, redox reactions, and cation exchange in the Wilcox and/or adjoining confining units. Accompanying trends in deuterium and oxygen-18 can be explained either by shifts in the stable isotopic composition of paleorecharge or by cross-formational leakage. Numerical modeling of groundwater flow and solute transport should resolve which of those processes is dominant.

Bengal Basin: An estimated 50 million residents of the Bengal basin in eastern India and Bangladesh face health risks from ingesting arsenic in shallow ground water. Arsenic appears to be released from sediments under anoxic conditions as iron oxides dissolve. Abhijit Mukherjee (PhD 2006) used data from a network of public water-supply wells to develop regional-scale models of ground-water flow and chemical evolution in the Indian state of West Bengal. Groundwater is recharged primarily during the monsoon season. Regional groundwater flow toward the Bay of Bengal has been perturbed by extensive pumping for irrigation, which could have caused arsenic contamination of some deep public wells. Processes controlling groundwater chemistry include carbonate dissolution, silicate weathering, cation exchange, redox reactions, and mixing with saline water.

High Plains (Ogallala) Aquifer: The High Plains aquifer is the largest aquifer in the USA and an important resource for agricultural, industrial, and municipal uses. Sunil Mehta (PhD 2000) documented that salinization northeast of Amarillo, Texas, results mainly from upward seepage of relatively shallow brines into the High Plains aquifer and not leakage of deeper brines produced with oil and gas. Elsewhere in the region, the composition of groundwater in the High Plains aquifer is controlled primarily by processes occurring during recharge, including depression-focused infiltration, evapotranspiration, and carbon cycling in the vadose zone. Denitrification limits nitrate loading to groundwater and thus facilitates the use of waste water for artificial recharge.

(Left: Abhijit Mukherjee uses a colorimetric technique to measure the concentration of ferrous iron in the Canning public-supply well, June 2004.
Right: Sunil Mehta collects brine from an oil well in Carson County, Texas, August 1997.) 

Sediment and pathogen transport in Inner Bluegrass karst ground-water basins
Groundwater flow along bedding planes and fractures in limestone results in dissolution of the rock, evolution of conduits, and development of an integrated surface and subsurface drainage network. Consequently, subsurface transport of sediment and pathogens can occur as a result of storms. With colleagues in Plant and Soil Science, Civil Engineering, and the Kentucky Geological Survey, Todd McFarland (MS 2003), Tom Reed (MS 2006), and James Ward (PhD 2008) studied discharge, water chemistry, pathogen concentrations, and sediment characteristics for two springs (one mainly urban, one rural) in Woodford County, Kentucky. Microbial results are consistent with differences in land use. Suspended sediment consists mainly of silt-sized detrital quartz, and the urban spring appears to respond more rapidly to precipitation than the rural spring does.

(Blue Hole spring, May 2002.)

Ground-water/surface-water interactions in the Gulf Coastal Plain of western Kentucky
Paducah Gaseous Diffusion Plant (PGDP): Contaminated groundwater from the U.S. Department of Energy's Paducah Gaseous Diffusion Plant (PGDP), a Superfund site in McCracken County, Kentucky, discharges via springs to Little Bayou Creek, which flows through a state wildlife management area. Eric Wallin (MS 1998), Abhijit Mukherjee (MS 2003), and Danita LaSage (PhD 2004) quantified spatial and temporal variability in seepage along Little Bayou Creek. Josh Sexton (MS 2006) constructed a conceptual stratigraphic model of the site. Locations of springs appear to be controlled by stratigraphic heterogeneities, stream channelization, and possibly faults. Spring-flow rates and trichlorethene (TCE) concentrations in the stream tend to decrease from May through January, then rebound.

Ledbetter Creek: With colleagues at Murray State's Center for Reservoir Research, Karen Thompson (MS 2002) and Todd Aseltyne (PhD candidate) studied the influence of reservoir-level manipulation on ground-water flow within the Ledbetter Creek watershed in Calloway County, Kentucky. Ledbetter Creek is a tributary to Kentucky Lake, the terminal reservoir on the Tennessee River. Water-level monitoring of piezometers and wells and gauging of stream and spring flow indicates that ground water discharges to Ledbetter Creek and within the creek's embayment. As at PGDP, discharge rates and water levels in wells tend to be highest in late spring and lowest in early winter. Within the embayment itself, the hydraulic gradient is reversed from upward to downward when the embayment is submerged between April and September.

(Left: Andrea Hougham [undergraduate assistant] and Danita LaSage collect samples from a sand boil [submerged spring] in Little Bayou Creek, May 2000.
Right: Danita and Andrea monitor water levels in piezometers in Ledbetter embayment, May 2000.)

Natural attenuation of trichloroethene in ground water and surface water
Monitored natural attenuation can be an option for remediating groundwater contamination, particularly for chlorinated hydrocarbons such as TCE, a common solvent and suspected carcinogen. David Butler (MS 1999) and Nadege Etienne (MS [Plant and Soil Science] 1999) identified methanogenic bacteria, which have been shown to be capable of degrading TCE at other sites, in soils and sediments like those bounding the contaminated regional gravel aquifer in the vicinity of PGDP. However, biodegradation was insignificant in batch cultures over periods as long as 10 months, perhaps because of a lack of nutrients or a lack of acclimation to TCE. Abhijit Mukherjee (MS 2003) and Danita LaSage (PhD 2004) found that volatilization and dilution limit TCE concentrations in Little Bayou Creek.

(Abhijit Mukherjee collects samples during Little Bayou Creek tracer test, January 2002.)


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Updated 27 August 2008